1.
Biosci Biotechnol Biochem
; 84(6): 1113-1118, 2020 Jun.
Artigo
em Inglês
| MEDLINE
| ID: mdl-32116121
RESUMO
Heliolactone is one of the earliest identified non-canonical strigolactones. Its concise synthesis was achieved by employing Knoevenagel-type condensation and semi-reduction of a malonate intermediate as the key steps. This synthesis was performed in a non-stereoselective manner, and thus a racemic and diastereomeric mixture of heliolactone was obtained. The developed synthetic route is fairly concise and straightforward.